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Synthesis, characterization and fluorescent performance studies of novel diphenyl sulfone-functionalized water-soluble polymer
Author(s) -
Bin Wang,
Jing Ma,
Xiangmei Ma
Publication year - 2020
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc200407041w
Subject(s) - sulfone , fluorescence , polymer , proton nmr , quenching (fluorescence) , chemistry , fluorescence spectroscopy , hydrothermal circulation , nuclear chemistry , combinatorial chemistry , polymer chemistry , photochemistry , organic chemistry , chemical engineering , physics , quantum mechanics , engineering
In this communication, a novel water-soluble diphenyl sulfone-functionalized polymer was successfully synthesized through a facile hydrothermal synthesis route and then characterized by FT-IR, UV?Vis, 1H-NMR and 13C- -NMR spectroscopy. Fluorescence quenching experiments revealed that the fluorescence intensities of the resulting diphenyl sulfone-functionalized polymers were linear with the concentrations of Fe3+ and 4-nitrophenol (4-NP) in the concentration ranges of (5.0?24.9)?10-8 and (5.0?50.0)?10-7 mol dm-3, with detection limits of 2.8?10-8 and 2.2?10-7 mol dm-3, respectively. These results created opportunities for the development of novel chemosensors by introducing selective fluorescent groups into polymeric materials.

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