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One-pot preparation of carbamoyl benzotriazoles and their applications in the preparation of ureas, hydrazinecarboxamides and carbamic esters
Author(s) -
Hui Mao,
Huili Liu,
Yawei Tu,
Zhiyun Zhong,
Xin Lv,
Xiaoxia Wang
Publication year - 2015
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc150126069m
Subject(s) - carbamic acid , chemistry , benzotriazole , reactivity (psychology) , organic chemistry , carbamate , combinatorial chemistry , medicine , alternative medicine , pathology
Carbamoyl benzotriazoles were conveniently synthesized in one-pot from carboxylic acids, diphenylphosphorazidate (DPPA) and benzotriazole (BtH). The reactivity and applications of carbamoyl benzotriazoles were also explored. Carbamoyl benzotriazoles react smoothly with amino acids, hydrazines and alcohols respectively, thus providing facile access to the corresponding ureas, hydrazinecarboxamides and carbamic esters in good to excellent yields

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