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Diphenylamine (DPA) in ethanol on the surface of ZrO2 undergoes photoinduced   oxidative transformation yielding N-phenyl-p-benzoquinonimine (PBQ). The   light-induced transformation on ZrO2 enhances with [DPA], ZrO2-loading,   airflow rate and photon flux. The formation of PBQ on ZrO2 is larger on   illumination at 254 nm than at 365 nm. The ZrO2 is reusable without any   treatment. The mechanism of light-induced oxidative transformation of DPA on   ZrO2 has been discussed with appropriate kinetic law. ZnO and ZnS enhance the   UV light-induced transformation of DPA on ZrO2 indicating synergism

Light-induced oxidative transformation of diphenylamine on ZrO2. Synergism by ZnO and ZnS