Anatase titania-vanadium polyphosphomolybdate as an efficient and reusable nano catalyst for desulphurization of gas oil | Zendy

Mohammad Ali Rezvani | Zendy; Shojaei Fallah | Zendy; Zonoz Mohamadi | Zendy

Open Access

Anatase titania-vanadium polyphosphomolybdate as an efficient and reusable nano catalyst for desulphurization of gas oil

Author(s) -

Mohammad Ali Rezvani,

Shojaei Fallah,

Zonoz Mohamadi

Publication year - 2014

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc131026015a

Subject(s) - vanadium , formic acid , anatase , hydrogen peroxide , catalysis , chemical engineering , sulfur , nano , chemistry , titanium , nanocomposite , materials science , inorganic chemistry , organic chemistry , nanotechnology , photocatalysis , engineering

(Bu4N)4H[PMo10V2O40]-TiO2 nanocomposite has been synthesized by a reaction of (Bu4N)4H[PMo10V2O40] with titanium tetraisopropoxide at 100 °C via sol-gel method. The crushed nano layer of anatase phase is 20 nm in nature and fixing of (Bu4N)4H[PMo10V2O40] decreases its size. This nano Polyphosphomolybdate was shown be able to oxidative desulphurization of simulated gas oil with high S conversion (more than 98%). In the present work, efficient oxidative desulphurization of gas oil and simulated gas oil with formic acid/hydrogen peroxide system is reported. This system provides an efficient, convenient and practical method for scavenging sulfur compound

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