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An efficient and mild method for the synthesis of spiro [1,3-  oxathiolan/oxathianes] in the solid state reaction at room temperature has  been described. This method is a good option to obtain the title compounds  in quantitative yields in a simple and inexpensive way. Applying this  methodology, different thia heterocycles were synthesized

A facile catalyst and solvent-free synthesis of spiro thia heterocycles on grinding