Derived thermodynamic properties of alcohol + cyclohexylamine mixtures | Zendy

Ivona R. Radović | Zendy; Mirjana Lj. Kijevčanin | Zendy; Aleksandar Tasić | Zendy; Bojan D. Djordjević | Zendy; Slobodan Šerbanović | Zendy

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Derived thermodynamic properties of alcohol + cyclohexylamine mixtures

Author(s) -

Ivona R. Radović,

Mirjana Lj. Kijevčanin,

Aleksandar Tasić,

Bojan D. Djordjević,

Slobodan Šerbanović

Publication year - 2010

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc1002283r

Subject(s) - dilution , enthalpy , molar , chemistry , thermal expansion , thermodynamics , partial molar property , molar volume , alcohol , isothermal process , cyclohexylamine , primary alcohol , organic chemistry , methanol , medicine , dentistry , physics

Thermal expansion coefficients, α, excess thermal expansion coeffi- cients, α E , isothermal coefficients of pressure excess molar enthalpy, (∂H E /∂p)T,x, i V ∞ , were calculated using experimental densities and excess molar volumes, E V , data. All calculations are performed for the binary systems of cyclohexylamine with 1-propanol or 1-butanol or 2-butanol or 2-methyl-2-pro- panol. The Redlich-Kister polynomial and the reduced excess molar volume approach were used in the evaluation of these properties. In addition, the aim of this investigation was to provide a set of various volumetric data in order to asses the influence of temperature, chain length and position of hydroxyl group in the alcohol molecule on the molecular interactions in the examined binary

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