Stereoselective cyclo-addition reactions of azomethine ylides catalysed by in situ generated Ag(I)/bisphosphine complexes | Zendy

Ronald Grigg | Zendy; Suren Husinec | Zendy; Vladimir Savić | Zendy

Open Access

Stereoselective cyclo-addition reactions of azomethine ylides catalysed by in situ generated Ag(I)/bisphosphine complexes

Author(s) -

Ronald Grigg,

Suren Husinec,

Vladimir Savić

Publication year - 2010

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc1001001g

Subject(s) - stereoselectivity , pyrrolidine , in situ , chemistry , yield (engineering) , medicinal chemistry , reaction conditions , catalysis , stereochemistry , organic chemistry , materials science , metallurgy

Stereoselective cyclo-addition reactions of azomethine ylides pro- moted by in situ generated Ag(I)/bisphosphine complexes were studied. Under the optimised conditions, the pyrrolidine products were isolated in up to 84 % yield and with up to 71 % e.e. The effects of various reaction variables on the stereoselectivity were also investigated.

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