English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

The reaction of K2(PdCl4) with (S,S)-(i-Pr)2eddip diester (diisopropyl (S,S)-2,2'-(1,2-ethanediyldiimino)dipropanoate) resulted in {PdCl2((S,S)-(i- -Pr)2eddip-κ 2 N,N')} (1) and {PdCl((S,S)-(i-Pr)eddip-κ 2 N,N',κO)} (2) with one hydrolyzed ester group. The compounds were characterized by spectroscopic me- thods and it was proved that the reaction is diastereoselective ( 1 H- and 13 C-NMR) in the case of 2 (one diastereoisomer of four possible). The structure of 2 was determined by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N' configured isomer. In contrast, the reaction yielding 1 produced two of three possible diastereoisomers. DFT calculations support the formation of two diastereoisomers of 1 and of one diastereoisomer of 2.

Palladium(II) complexes with R2edda derived ligands, Part I: Reaction of diisopropyl (S,S)-2,2'-(1,2-ethanediyldiimino)- dipropanoate with K2[PdCl4]