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Periodic current oscillations of zinc in nitric acid solutions
Author(s) -
Florin Crisan,
Ervin Salló
Publication year - 2008
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0802221c
Subject(s) - nitric acid , zinc , potassium hydroxide , chemistry , nitric oxide , inorganic chemistry , potassium dichromate , current (fluid) , precipitation , dissolution , anode , cyclic voltammetry , electrode , electrochemistry , physics , organic chemistry , meteorology , thermodynamics
: This paper presents current oscillations of a Zn anode in solutions of nitric acid and potassium dichromate. The effects of the nitric acid concentration were investigated. The system was analyzed using cyclic voltammetry, current-time plots and attractors. It was found that the concentration of nitric acid has a major effect on the behavior of the system and it is proposed that zinc hydroxide precipitation-dissolution processes are responsible for the current oscillations.

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