The charge percolation mechanism and simulation of Ziegler-Natta polymerizations, part VI: Mechanism of ethylene polymerization by supported chromium oxide | Zendy

Dragoslav Stoiljković | Zendy; Branka Pilić | Zendy; Misa Bulajic | Zendy; Nebojs̃a Djurasović | Zendy; Nikolaj Ostrovski | Zendy

Open Access

The charge percolation mechanism and simulation of Ziegler-Natta polymerizations, part VI: Mechanism of ethylene polymerization by supported chromium oxide

Author(s) -

Dragoslav Stoiljković,

Branka Pilić,

Misa Bulajic,

Nebojs̃a Djurasović,

Nikolaj Ostrovski

Publication year - 2007

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc0711155s

Subject(s) - polymerization , natta , percolation (cognitive psychology) , olefin polymerization , oxide , mechanism (biology) , materials science , chromium , ethylene oxide , polymer chemistry , chemistry , polymer , organic chemistry , copolymer , physics , quantum mechanics , neuroscience , biology

Despite intensive research over the last 50 years, many questions concer- ning ethylene polymerization by supported chromium oxide are still unanswered. Hence, the very fundamental issues of this polymerization are discussed in this paper. It is shown that a charge percolation mechanism (CPM) of olefin polymeri- zation by Ziegler-Natta transition metal complexes, recently proposed by us, can give the answers in this case, too.

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