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A new series of two types of acyclic binuclear Schiff base complexes, pre- pared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of NiII is a 1:1 type of electrolyte. All the complexes have sub-nor- mal magnetic moments in accordance with their binuclear nature. The thermal be- haviour of the complexes was studied by thermogravimetry.

journal of the serbian chemical society

The template synthesis, spectral characterization and thermal behavior of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandion