The template synthesis, spectral characterization and thermal behavior of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandion | Zendy

Mehmet Sönmez | Zendy; M. Şekerci | Zendy

Open Access

The template synthesis, spectral characterization and thermal behavior of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandion

Author(s) -

Mehmet Sönmez,

M. Şekerci

Publication year - 2007

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc0703259s

Subject(s) - schiff base , thermogravimetry , chemistry , electrolyte , magnetic susceptibility , condensation , conductivity , characterization (materials science) , base (topology) , thermal analysis , elemental analysis , inorganic chemistry , crystallography , thermal , materials science , nanotechnology , thermodynamics , electrode , mathematical analysis , physics , mathematics

A new series of two types of acyclic binuclear Schiff base complexes, pre- pared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of NiII is a 1:1 type of electrolyte. All the complexes have sub-nor- mal magnetic moments in accordance with their binuclear nature. The thermal be- haviour of the complexes was studied by thermogravimetry.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research