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Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane
Author(s) -
Hua Zhong,
Rong Zeng
Publication year - 2006
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0610049z
Subject(s) - catalysis , ethylenediaminetetraacetic acid , inorganic chemistry , decomposition , bet theory , citric acid , chemistry , amorphous solid , oxygen , hexane , particle size , catalytic oxidation , nuclear chemistry , materials science , crystallography , chelation , organic chemistry
Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPS meth- ods. Their catalytic behavior in the total oxidation of hexane was examined. The fol- lowing activity order was found LaSrCoO4 >L aSrNiO4 >L aSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxy- gen, particle size and BET surface area.

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