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Perovskite-type LaSrMO4 (M = Mn, Fe, Co, Ni, Cu) mixed oxides were prepared by the decomposition of amorphous citric and ethylenediaminetetraacetic acid complexes and investigated by the XRD, FTIR, BET, TPR, TPD and XPS meth- ods. Their catalytic behavior in the total oxidation of hexane was examined. The fol- lowing activity order was found LaSrCoO4 >L aSrNiO4 >L aSrCuO4 > LaSrFeO4 > LaSrMnO4. This is explained in terms of oxygen vacancies and mobile lattice oxy- gen, particle size and BET surface area.

Structure of LaSrMO4(M = Mn, Fe, Co, Ni, Cu) and their catalytic properties in the total oxidation of hexane