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The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns
Author(s) -
Dušan Mijin,
Dušan Antonović
Publication year - 2006
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0606629m
Subject(s) - chemistry , kovats retention index , alkyl , benzoic acid , cyclohexanecarboxylic acid , phenylacetic acid , capillary action , chromatography , analytical chemistry (journal) , organic chemistry , thermodynamics , gas chromatography , physics
The temperature dependence of the retention index was studied for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns. The study was performed over various temperature ranges depending on the volatility of the ester. Two linear equations of the temperature dependence of the retention data on the column temperature and its reciprocal as variables were studied. A good linearity of the retention index versus column temperature was found.

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