In vitro complexes of copper and zinc with chlorophyll
Author(s) -
Jelena Petrovic,
Goran Nikolić,
Dejan Marković
Publication year - 2006
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0605501p
Subject(s) - zinc , copper , chlorophyll , chemistry , chlorophyll a , chelation , photosynthesis , pigment , fourier transform infrared spectroscopy , photochemistry , inorganic chemistry , biochemistry , organic chemistry , chemical engineering , engineering
Complexes of copper and zinc with chlorophyll, the major photosynthesis pigment, were studied by Vis, FTIR and fluorescence spectroscopy. Two types of complexes were recognized. While copper replaces the central magnesium atom of chlorophyll to form a "central" Cu-Chl complex, this was not proposed in the case of zinc. Instead, the zinc-mediated formation of a 6-membered chelate cycle fused at the periphery of the chlorophyll structure is proposed. The latter event could be ascribed to allomerization reactions of chlorophyll.
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