Viscosities of binary mixtures of toluene with butan-1-ol and 2-methylpropan-2-ol
Author(s) -
Vasile Dumitrescu,
Octav Pântea
Publication year - 2005
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0511313d
Subject(s) - toluene , viscosity , thermodynamics , binary number , materials science , chemistry , organic chemistry , physics , mathematics , arithmetic
The viscosities of binary liquid mixtures of toluene with butan-1-ol and 2-methylpropan-2-ol have been determined at 298.15, 303.15, 308.15, 313.15 and 318.15 K over the whole concentration range. The Hind, Grunberg-Nissan, Wijk, Auslander and McAllister models were used to calculate the viscosity coefficients and these were compared with the experimental data for the mixtures. Excess vis- cosities were also calculated and fitted to the Redlich-Kister equation. Various ther- modynamic properties of viscous flow activation were determined and their varia- tions with composition are discussed.
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