Synthesis, as well as linear and nonlinear fluorescence properties of 5, 5’-bis(4-N-carbazolylstyryl)-2, 2’-bithiophene
Author(s) -
Xia Guang-ming,
Ping Lü,
Guibao Xu
Publication year - 2004
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0405335x
Subject(s) - excited state , fluorescence , quantum yield , absorption (acoustics) , photochemistry , materials science , luminescence , yield (engineering) , two photon excitation microscopy , laser , absorption cross section , two photon absorption , atomic physics , chemistry , cross section (physics) , optoelectronics , optics , physics , quantum mechanics , metallurgy , composite material
A new bithiophene-based organic luminescence material, named 5,5'-bis(4-N-carbazoylstyryl)-2,2'-bithiophene (BCSBT), was synthesized. Its single-photon excited fluorescence band is located in the range of 520-530 nm, witha quantum yield of around 10 %. The compound emits strong two-photon-excited fluorescence when excited by 200 fs laser pulses. The two-photon absorption cross section of BCSBT was found to be 124×10 - 5 0 cm 4 s by the two-photon-excited fluorescence method.
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