Termplate synthesis of Mn(II) complexes of tetraazamacrocycles derived from diaminoalkanes and 3, 4-hexanedione or benzil | Zendy

R. N. Prasad | Zendy; Nitin Gupta | Zendy

Open Access

Termplate synthesis of Mn(II) complexes of tetraazamacrocycles derived from diaminoalkanes and 3, 4-hexanedione or benzil

Author(s) -

R. N. Prasad,

Nitin Gupta

Publication year - 2003

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc0306455p

Subject(s) - benzil , chemistry , condensation , polymer chemistry , organic chemistry , catalysis , physics , thermodynamics

Template condensation of α-diketones. such as 3,4-hexanedione or benzil, with 1,n-diaminoalkanes (where n=4, 5, 6, 7, 8, 9, 10 or 12) in the presence of Mn(II) resulted in the formation of complexes of the type [MnL(NO 3 )]NO 3 (where L = 16 to 32-membered macrocycle). These complexes have been characterized by elemental analyses, conductances, magnetic measurements, as well as IR and electronic spectra.

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