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The aim of this work was to examine the disproportionation reaction of iodous acid, HOIO, in aqueous 0.18 mol/dm 3 H 2 SO 4 solution, by spectrophotometric measurements of the absorbance. The absorbing Hgl + -ion species were generated during the observed disproportionation process. The specific rate constants of disproportionation were calculated in the temperature range from 12 to 30°C. The average values ranged from 1.20 to 2.94 mol - 1 dm 3 s - 1 , respectively. In addition, the values ofthe activation energies were determined by a graphical method. An average value of 71.20 kJ/mol was found for the chosen temperature interval.

The temperature dependence of the disproportionation reaction of iodous acid in aqueous sulfuric acid solutions