Hydride reduction of B-norcholestane 5α,6α-epoxide | Zendy

Mira S. Bjelaković | Zendy; Vladimir B. Pavlović | Zendy; Ljubinka Lorenc | Zendy

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Hydride reduction of B-norcholestane 5α,6α-epoxide

Author(s) -

Mira S. Bjelaković,

Vladimir B. Pavlović,

Ljubinka Lorenc

Publication year - 2002

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc0202069b

Subject(s) - epoxide , lithium aluminium hydride , diol , reagent , hydride , chemistry , lithium (medication) , aluminum hydride , reduction (mathematics) , combinatorial chemistry , medicinal chemistry , organic chemistry , ion , catalysis , mathematics , biology , hydrogen , methoxide , endocrinology , geometry

B-Norcholestane epoxide 2 is reduced with lithium aluminium hydride to give either the 3β,6α-diol 3 or the corresponding 3β,5α-diol 4, depending on the quality of the reducing reagent employed. A plausible mechanistic explanation of the obtained results is suggested.

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