Characterization and carbon monoxide oxidation activity of La1.ySryCr1.xRuxO3 perovskites | Zendy

A. Terlecki-Baričević | Zendy; Srdjan Petrović | Zendy; D. Jovanović | Zendy; Ljiljana Karanović | Zendy; C. Marinova | Zendy

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Characterization and carbon monoxide oxidation activity of La1.ySryCr1.xRuxO3 perovskites

Author(s) -

A. Terlecki-Baričević,

Srdjan Petrović,

D. Jovanović,

Ljiljana Karanović,

C. Marinova

Publication year - 2000

Publication title -

journal of the serbian chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.227

H-Index - 45

eISSN - 1820-7421

pISSN - 0352-5139

DOI - 10.2298/jsc0001015t

Subject(s) - ruthenium , activation energy , stoichiometry , carbon monoxide , x ray photoelectron spectroscopy , chemistry , perovskite (structure) , inorganic chemistry , catalysis , analytical chemistry (journal) , crystallography , chemical engineering , biochemistry , chromatography , engineering

The oxidation of CO over La1-ySryCr1-xRuxO3 perovskite type oxides with y=0.3 and 0 £ x £0.100 have been studied. X-ray fluorescence analysis confirmed that content of elements in the bulk corresponds to the established nominal perovskite stoichiometry, indicating that no significant oxidation of ruthenium into volatile polyvalent oxides with their consequented escape from the sample occurred in air up to the temperature of 1000 oC. According to X-ray diffraction analysis, all sampls achieved the perovskite hexagonal with the presence of some SrCrO4. X-ray photoelectron spectroscopy analysis of ruthenium samples shows higher Ru and Sr surface concentraitions than in the bulk. The binding energy for Ru3p is virtually the same in all samples and consistent with that of Ru 4+ (463.6464.3eV). Kinetic studies were performed in a differential recycle reactor with a recycling ratio 80. The results show that substitution of Ru 4+ for

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