Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte | Zendy

I. Katayama | Zendy; Dragana Živković | Zendy; Dragan Manasijević | Zendy; Takao Oishi | Zendy; Živan Živković | Zendy; T. Iida | Zendy

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Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte

Author(s) -

I. Katayama,

Dragana Živković,

Dragan Manasijević,

Takao Oishi,

Živan Živković,

T. Iida

Publication year - 2002

Publication title -

journal of mining and metallurgy section b metallurgy

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.42

H-Index - 20

eISSN - 2217-7175

pISSN - 1450-5339

DOI - 10.2298/jmmb0204229k

Subject(s) - electrolyte , gallium , cubic zirconia , emf measurement , electrochemistry , materials science , activity coefficient , solid solution , analytical chemistry (journal) , standard deviation , thermodynamics , chemistry , chromatography , metallurgy , electrode , physics , mathematics , ceramic , statistics , aqueous solution

EMF measurement of the electrochemical cell with zirconia as solid electrolyte was performed to determine the gallium activity from 950 to 1150K in the entire composition range of liquid Ga-Pb alloys. In the whole concentration range, activity of Ga shows moderately positive deviations from ideality, and activity of Pb which is derived by Gibbs- Duhem equation shows also positive deviation from ideality. These are compared with published data obtained by different experimental methods

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