Cloud point extraction procedure for preconcentration and determination of lead(II) ions using triton X-100 at room temperature | Zendy

Mersiha Suljkanović | Zendy; Jasmin Suljagić | Zendy; Nusreta Hasić | Zendy; Selmina Hodzic | Zendy

Open Access

Cloud point extraction procedure for preconcentration and determination of lead(II) ions using triton X-100 at room temperature

Author(s) -

Mersiha Suljkanović,

Jasmin Suljagić,

Nusreta Hasić,

Selmina Hodzic

Publication year - 2019

Publication title -

acta periodica technologica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.134

H-Index - 15

eISSN - 2406-095X

pISSN - 1450-7188

DOI - 10.2298/apt1950286s

Subject(s) - cloud point , chemistry , extraction (chemistry) , triton x 100 , electrolyte , analytical chemistry (journal) , ion , chromatography , pulmonary surfactant , biochemistry , organic chemistry , electrode

A Cloud point extraction (CPE) procedure was presented for preconcentration of lead(II) ions, after complexation by 18-crown-6 (18C6) and extraction with Triton X-100 at proposed experimental conditions. After separation of surfactant - rich phase, content of Pb(II) ions in remaining solution was measured by Flame Atomic Absorption Spectrometry (FAAS). The experimental conditions such as pH, temperature, concentration of Triton X-100, concentration of 18C6, incubation time, type and concentration of added electrolyte, were evaluated. Results showed that among investigated electrolytes (NaCl, Na2SO4 and Na2CO3) the amount of 0.9 mol/L Na2CO3 lowers cloud point temperature of Triton X-100 to 22?C (room temperature during the experiment), thus simplifying the extraction procedure. After an incubation time of 5 minutes and using the concentration of 1.2?10-3 mol/L Triton X-100 and 1.5?10-4 mol/L 18C6 (1:1 stoichiometric ratio for 18C6:Pb), 60% of lead (II) ions were efficiently removed from investigated solution.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research