Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative | Zendy

Suzana Cakić | Zendy; Goran Nikolić | Zendy; Jakov Stamenković | Zendy; Sandra Konstantinović | Zendy

Open Access

Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative

Author(s) -

Suzana Cakić,

Goran Nikolić,

Jakov Stamenković,

Sandra Konstantinović

Publication year - 2005

Publication title -

acta periodica technologica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.134

H-Index - 15

eISSN - 2406-095X

pISSN - 1450-7188

DOI - 10.2298/apt0536091c

Subject(s) - hydroxylamine , ligand (biochemistry) , derivative (finance) , chemistry , fourier transform infrared spectroscopy , maleic acid , polymer chemistry , nuclear chemistry , organic chemistry , physics , copolymer , biochemistry , receptor , financial economics , economics , polymer , quantum mechanics

Two new Mn(III) mixed-ligand complexes with two acetylacetonate (acac) ligands and one maleate ligand and its hydroxylamine derivative of the general formula [Mn(C5H7O2)2L] were prepared. Their structure was established by using elemental analysis, FTIR and UV/VIS spectroscopic methods, as well as magnetic measurement. Replacement of the acetylacetonate ligand by the corresponding acid ligand has been confirmed in Mn(III) acetylacetonate. Based on the obtained experimental data and literature indications, structural formulae to these compounds were assigned

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