Synthesis of some diol DErivatives as potential reagents in steroid chemistry | Zendy

Katarina PenovGasi | Zendy; Ksenija Kuhajda | Zendy; Stanko Cvjetićanin | Zendy; Evgenija A. Djurendić | Zendy; Ljubica MedićMijačevic | Zendy; Vjera Pejanović | Zendy; Marija N. Sakač | Zendy

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Synthesis of some diol DErivatives as potential reagents in steroid chemistry

Author(s) -

Katarina PenovGasi,

Ksenija Kuhajda,

Stanko Cvjetićanin,

Evgenija A. Djurendić,

Ljubica MedićMijačevic,

Vjera Pejanović,

Marija N. Sakač

Publication year - 2003

Publication title -

acta periodica technologica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.134

H-Index - 15

eISSN - 2406-095X

pISSN - 1450-7188

DOI - 10.2298/apt0334111p

Subject(s) - reagent , chemistry , diol , alkyl , steroid , dehydroepiandrosterone , carbonyl group , organic chemistry , medicinal chemistry , stereochemistry , hormone , biochemistry , androgen

The multistage syntheses of the p-toluenesulphonyloxy esters (1-benzyloxy-4-p-toluenesulphonyloxybutane (3a) 1-benzyloxy-6-p-toluenesulphonyloxyhexane (3b) and 1-benzyloxy-10-p-toluenesulphonyloxydecane (3c)(, alkyl chlorides (1-benzyloxy-4-chlorobutane (4a), 1-benzyloxy-6-chlorohexane (4b) and 1-benzyloxy-10-chlorodecane (4c)(, as well as alkyl iodides (1-benzyloxy-4-iodobutane (5a), 1-benzyloxy-6-iodohexane (5b) and 1-benzyloxy-10-iododecane (5c)( with the terminal O-benzyl groups starting from 1,4-butanediol (1a), 1,6-hexanediol (1b) and 1,10-decanediol (1c) were carried out. The possibilities of formation and addition of the corresponding Grignard reagent to the C-17 carbonyl group of dehydroepiandrosterone were investigated

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