Study The Rate Constant of Photodecomposition of Polystyrene Films in Presence of Some 4- amino-5-(2-(6-methoxynaphthalen-2-yl)piperidino)-1,2,4- triazole-3-thion Complexes
Author(s) -
Adil A. Awad,
Rehab A. M. Al-Hasani,
Emad͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏ Yousif
Publication year - 2016
Publication title -
journal of al-nahrain university-science
Language(s) - English
Resource type - Journals
eISSN - 2519-0881
pISSN - 1814-5922
DOI - 10.22401/jnus.19.1.08
Subject(s) - photodegradation , polystyrene , chloroform , chemistry , solvent , reaction rate constant , polymer chemistry , photochemistry , organic chemistry , kinetics , catalysis , polymer , photocatalysis , physics , quantum mechanics
The photostabilization of polystyrene (PS) films by (4-amino-5-(2-(6-methoxynaphthalen-2-yl)piperidino)-1,2,4-triazole-3-thion(L) compounds was investigated. PS films containing concentration of complexes 0.5% by weight were produced by the casting method from chloroform as a solvent. The photostabilization activities of these compounds were determined by monitoring the carbonyl and hydroxyl indices with irradiation time. The photostabilization of PS films by prepared complexes was investigated. The PS films containing concentration of complexes 0.5% by weight were produced by the casting method from (CHCl3) solvent. The photodegradation of the obtained films was investigated using UV-vis. spectra. The photostabilization activity of these compounds was determined by calculating the photodecomposition rate constant (kd) for the modified PS.
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