Investigation of the Properties of Polymer Bonded Explosives Based on 1,1-Diamino-2,2-dinitroethene (FOX-7) and 1,3,5,7-Tetranitro-1,3,5,7-tetraazacyclooctane (HMX)
Author(s) -
Z. Chyłek,
Robert Jurkiewicz
Publication year - 2016
Publication title -
central european journal of energetic materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 25
eISSN - 2353-1843
pISSN - 1733-7178
DOI - 10.22211/cejem/67226
Subject(s) - explosive material , materials science , polymer science , polymer , thermodynamics , polymer chemistry , chemical engineering , chemistry , composite material , organic chemistry , physics , engineering
The influence of polymeric matrices on the physical properties and stability of polymer bonded explosives based on FOX-7 (1,1-diamino-2,2dinitroethene) and HMX (1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane) was investigated. Samples of explosives were prepared with different polymeric additives e.g. nonylphenylpolyoxyethyleneglycol ethers (ROKAFENOL), silicone greases and poly(3-methyl-3-nitroxymethyloxetane) (Poly(NIMMO)). The mass ratio of polymeric matrices to explosives was determined experimentally in order to obtain plastic samples stable at room temperature. The most promising products were tested for sensitivity to mechanical and thermal stimuli. Determinations of the critical diameter and detonation velocity were also performed. The use of silicone grease in the mixture containing Poly(NIMMO) gave the most desirable results, that is to say a combination of high performance and high stability.
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