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Spectrophotometric Determination of the CuSO<sub>4</sub> Soret Coefficient of a CuSO<sub>4</sub>-H2O Binary Solutions System
Author(s) -
Ijang Rohman,
Djaka Sasmita,
Iip Izul Falah
Publication year - 2010
Publication title -
indonesian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.273
H-Index - 14
eISSN - 2460-1578
pISSN - 1411-9420
DOI - 10.22146/ijc.21946
Subject(s) - chemistry , thermophoresis , molality , analytical chemistry (journal) , binary number , transmittance , chromatography , thermodynamics , thermal , aqueous solution , arithmetic , mathematics , optics , nanofluid , physics
A spectrophotometric technique for the determination of the CuSO 4 soret coefficient of a CuSO 4 -water binary solutions system is described. A short column of solutions is placed between horizontal metal plates that are held at different temperatures. The subsequent changes in composition due to thermal diffusion are followed by monitoring changes of transmittance near the end of the solutions column. In water, CuSO 4 diffuses to the warm compartment of column. The soret coefficient of CuSO 4 0.0254 molal in water agrees with the appropriate theory, i.e. 17.60x10 -3 ° C -1 on the average.

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