INTERPRETATION OF OXYGEN –18 ISOTOPE IN SULPHATE FROM DEEP GROUNDWATER IN JAKARTA AREA | Zendy

E. Ristin Pujiindiyati | Zendy; Wandowo Wandowo | Zendy; Zainal Abidin | Zendy

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INTERPRETATION OF OXYGEN –18 ISOTOPE IN SULPHATE FROM DEEP GROUNDWATER IN JAKARTA AREA

Author(s) -

E. Ristin Pujiindiyati,

Wandowo Wandowo,

Zainal Abidin

Publication year - 2010

Publication title -

indonesian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.273

H-Index - 14

eISSN - 2460-1578

pISSN - 1411-9420

DOI - 10.22146/ijc.21709

Subject(s) - δ18o , seawater , groundwater , isotopes of oxygen , chemistry , oxygen , environmental chemistry , dissolution , mineralogy , evaporite , δ34s , oxygen isotope ratio cycle , geology , stable isotope ratio , nuclear chemistry , hydrothermal circulation , carbonate , oceanography , fluid inclusions , geotechnical engineering , organic chemistry , seismology , physics , quantum mechanics

It has been done a determination of δ O (SO4) and δ O (H2O) value from Jakarta deep groundwater with depth 40-140 m. The aim of this research is to know some procesess influencing the composition of oxygen isotope in groundwater sulphate. A method commonly used to determine δ O (H2O) value is according to Epstein-Mayeda. CO2 gas resulted from equilibration process between water sample and CO2 gas standard in which oxygen isotopic reaction has occurred, is injected to mass spectrometer. For determination of δ O (SO4) value, Rafter method is used. CO2 gas released from reducing sulphate of water sample with graphite is injected to mass spectrometer. The results of δ O (H2O) values obtained in this experiment have a narrow range from -5,04 /00 to –6,65 /00 SMOW whereas their δO (SO4) values have a wider range from +8,3 /00 to +17,4 /00 SMOW. The more constant values of δ O (H2O) performed that evaporation effects might not occur. Based on the similarity between δO (SO4) values of deep groundwater and that of marine evaporite sulphate rocks, it is supposed that sulphate of Jakarta deep groundwater was derived from dissolution of this rocks. There was an indication of seawater intrusion around Pejagalan and Kamal Muara Penjaringan area based on the similarity between their δO (SO4) values and δO (SO4) of modern seawater. The contribution of oxygen from water in sulphide oxidation reaction ranged 0% to 12% suggesting that oxygen in deep groundwater sulphate was mainly derived from atmospheric molecular oxygen

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