Open AccessELECTROCHEMICAL SYNTHEZIS AND CHARACTERIZATION OF POLYPYRROLE FOR DODECYLSULFATE SENSOR MEMBRANE
Author(s) -
Abdul Haris Watoni,
Suryo Gandasasmita,
Indra Noviandri,
Buchari Buchari
Publication year - 2010
Publication title -
indonesian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.273
H-Index - 14
eISSN - 2460-1578
pISSN - 1411-9420
DOI - 10.22146/ijc.21665
Subject(s) - polypyrrole , chemistry , cyclic voltammetry , electrode , conductive polymer , supporting electrolyte , detection limit , electrochemistry , electrolyte , aqueous solution , monomer , dopant , inorganic chemistry , voltammetry , analytical chemistry (journal) , polymer , chromatography , doping , organic chemistry , materials science , optoelectronics
A conducting polymer, polypyrrole, has been electrochemically synthesized from pyrrole monomer using cyclic voltammetry technique in aqueous solution in the presence of HDS dopant and KNO3 supporting electrolyte. The polymer was deposited on the surface of an Au-wire and the modified electrode obtained was then used as dodecylsulfate (DS - ) ion sensor electrode. The best performance PPy-DS modified-Au electrode conditioned in the air system without HDS or SDS solution gave linear potential response for the concentration range of 1.0 x 10 -5 – 1.0 x 10 -3 M, sensitivity of 54.5 mV/decade, detection limit of 1.0 x 10 -5 M, and response time of 23 – 30 second. The electrode showed good selectivity towards other anions, therefore can be used to determine SDS concentration in real samples system without any change of the samples matrix.
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