The Acid Catalyzed Reaction of α-Pinene Over Y-Zeolite
Author(s) -
Nanik Wijayati,
Harno Dwi Pranowo,
Jumina Jumina,
Triyono Triyono
Publication year - 2013
Publication title -
indonesian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.273
H-Index - 14
eISSN - 2460-1578
pISSN - 1411-9420
DOI - 10.22146/ijc.21327
Subject(s) - chemistry , catalysis , isomerization , selectivity , zeolite , isopropyl alcohol , alcohol , pinene , terpineol , organic chemistry , nuclear chemistry
The hydration of α-pinene has been studied in the presence of Y-zeolite (Si/Al = 2.89) as a solid acid catalyst. The reaction was performed in batch reactor in isopropyl alcohol at various temperature and reaction time with magnetic stirrer. The acid catalyst hydration reaction of a-pinene yields a complex mixture of monoterpenes, alcohols and hydrocarbons. The selectivity of α-terpineol (the monocyclic alcohol) as main product was 59.20% with a conversion of 83.83% and the non alcoholic as the isomerization co-product as 30% after 60 min at 65 °C. The conversion and selectivity to α-terpineol increase significantly with in increase in temperature and reaction times.
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