On the two-domain equations for gas chromatography.
Author(s) -
Louis A. Romero,
Michael L. Parks
Publication year - 2009
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/978912
Subject(s) - partition (number theory) , partition coefficient , thermal diffusivity , stationary phase , chemistry , domain (mathematical analysis) , physics , analytical chemistry (journal) , chromatography , thermodynamics , mathematical analysis , mathematics , combinatorics
We present an analysis of gas chromatographic columns where the stationary phase is not assumed to be a thin uniform coating along the walls of the cross section. We also give an asymptotic analysis assuming that the parameter {beta} = KD{sup II}{rho}{sup II}/D{sup I}{rho}{sup I} is small. Here K is the partition coefficient, and D{sup i} and {rho}{sup i}, i = I, II are the diffusivity and density in the mobile (i = I) and stationary (i = II) regions
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