The Supramolecular Chemistry of Selective Anion Recognition for Anions of Environmental Relevance
Author(s) -
Jonathan L. Sessler
Publication year - 2004
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/850321
Subject(s) - sulfate , supramolecular chemistry , chemistry , relevance (law) , pyridine , nitrate , combinatorial chemistry , selectivity , solubilization , key (lock) , computer science , organic chemistry , molecule , biochemistry , political science , catalysis , law , computer security
In this first year of funding, progress has been made towards the stated project goal of generating useful sulfate extractants. A new series of bispyrrole-pyridine sulfate anion receptors was discovered and found to show very high sulfate-to-nitrate selectivity, a key prerequisite to generating a useful extractant. Progress was made towards developing the synthetic methodology needed to solubilize this system and other known receptors prepared by project collaborator, Prof. Kristin Bowman-James
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