Miniature Chemical Sensor combining Molecular Recognition with Evanescent Wave Cavity Ring-Down Spectroscopy
Author(s) -
Andrew C. R. Pipino,
Curtis W. Meuse
Publication year - 2003
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/834664
Subject(s) - spectroscopy , cavity ring down spectroscopy , evanescent wave , chemical sensor , materials science , chemistry , analytical chemistry (journal) , optoelectronics , nanotechnology , physics , environmental chemistry , electrode , quantum mechanics
To address the chemical sensing needs of DOE, a new class of chemical sensors is being developed that enables qualitative and quantitative, remote, real-time, optical diagnostics of chemical species in hazardous gas, liquid, and semi-solid phases by employing evanescent wave cavity ring-down spectroscopy (EW-CRDS). The feasibility and sensitivity of EW-CRDS was demonstrated previously under Project No.60231. The objective of this project is to enhance the selectivity and domain of application of EW-CRDS. Selectivity is enhanced by using molecular recognition (MR) chemistry and polarized ''fingerprint'' near-IR spectroscopy, while the domain of application is expanded by combining EW-CRDS with the unique optical properties of nanoparticles and by extending the technique to liquids
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