Precipitation and Deposition of Aluminum-Containing Phases in Tank Wastes
Author(s) -
Jun Liu,
Daniel M. Dabbs,
D.T. Hobbs
Publication year - 1999
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/833287
Subject(s) - leaching (pedology) , dissolution , precipitation , deposition (geology) , nucleation , homogeneous , aluminium , salt (chemistry) , materials science , chemical engineering , metallurgy , environmental science , chemistry , thermodynamics , engineering , geology , meteorology , soil science , organic chemistry , paleontology , physics , sediment , soil water
The goal of this work is to understand the kinetics of dissolution, precipitation, and scale formation involving aluminum-containing phases in alkaline salt solutions representative of tank wastes. This research will identify aluminum-containing phases that are likely to form or be present, and predict conditions under which such phases are likely to form or be present. Experiments will identify processing conditions that either promote or inhibit the heterogeneous or homogeneous nucleation and growth of aluminum-containing phases to form precipitates or scales. Test conditions will encompass conditions anticipated for waste storage, washing, leaching, concentration in evaporators, and contact with pipes, ion exchangers, and other processing media
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