Energies of organic compounds. Technical progress report | Zendy

Kent Wiberg | Zendy

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Energies of organic compounds. Technical progress report

Author(s) -

Kent Wiberg

Publication year - 1987

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/82275

Subject(s) - alkyl , chemistry , hydrolysis , carbonyl group , organic chemistry , group (periodic table) , standard enthalpy of formation , medicinal chemistry

A procedure was developed for carbonyl group reduction using triethylborohydride. Esters and lactones are readily reduced and are suitable as substrates. Some enthalpies of hydrolysis of lactones and esters were measured. Heats of trifluoroacetolysis of alkenes leading to tertiary alcohols were measured; some cyclic systems were also investigated. In order to study the effect of {alpha}-alkyl substituents on ketones, rotational barriers adjacent to carbonyl groups were studied

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