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CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE
Author(s) -
Gary T. Rochelle,
Eric Chen,
Jenna Cullinane,
Marcus Hilliard,
Terraun Jones
Publication year - 2003
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/821854
Subject(s) - potassium carbonate , chemistry , alkanolamine , solvent , non random two liquid model , absorption (acoustics) , potassium , stripping (fiber) , electrolyte , aqueous solution , inorganic chemistry , chromatography , materials science , organic chemistry , activity coefficient , electrode , composite material
The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. A rigorous thermodynamic model has been developed with a stand-alone FORTRAN code to represent the CO{sub 2} vapor pressure and speciation of the new solvent. Parameters have been developed for use of the electrolyte NRTL model in AspenPlus. Analytical methods have been developed using gas chromatography and ion chromatography. The heat exchangers for the pilot plant have been ordered

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