Final Technical Report [Polynuclear aromatic hydrocarbons with curved surfaces: Models and precursors for fullerenes] | Zendy

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Final Technical Report [Polynuclear aromatic hydrocarbons with curved surfaces: Models and precursors for fullerenes]

Author(s) -

Peter W Radideau

Publication year - 2001

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/810270

Subject(s) - corannulene , fullerene , hydrocarbon , transition metal , chemistry , nanotechnology , materials science , computational chemistry , organic chemistry , catalysis

Highlights of selected achievements are briefly outlined. The bowl-to-bowl inversion barrier was measured for a hydrocarbon on the C{sub 60} surface larger than corannulene; {Delta}G was determined to be 27.8 kcal/mol. A new route to the preparation of tetraketone involving benzeneseleninic anhydride was developed that represents a significant improvement in the overall process making semibuckminsterfullerene more accessible. The first crystallographically characterized transition metal buckybowl compound was reported

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