Metal alkoxides: templates for organometallic chemistry and catalysis. Final technical report on DE FG 02-86ER13570 | Zendy

Malcolm H. Chisholm | Zendy

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Metal alkoxides: templates for organometallic chemistry and catalysis. Final technical report on DE FG 02-86ER13570

Author(s) -

Malcolm H. Chisholm

Publication year - 2002

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/808502

Subject(s) - alkoxide , chemistry , catalysis , group 2 organometallic chemistry , tungsten , organometallic chemistry , triple bond , metal , polymer chemistry , polymerization , zinc , inorganic chemistry , molybdenum , magnesium , crystallography , organic chemistry , molecule , double bond , polymer

The physical properties and chemical reactivities of a series of alkoxide, fluoroalkoxide and thiolate compounds of molybdenum and tungsten having M{triple_bond}M or M{triple_bond}N bonds have been examined which reveal the influence of the pi-donor properties of the ligands: RO > R{sub f}O{approx}RS. Single-site metal alkoxide catalysts for the ring-opening polymerization of lactides have been prepared for the metals magnesium, zinc, and aluminum

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