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Energy Efficient Catalytic Reaction and Production of Cumene
Author(s) -
Russell L. Jarek,
Steven M. Thornberg,
STACIA BARROW,
Daniel E. Trudell,
Tina M. Nenoff
Publication year - 2001
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/791886
Subject(s) - cumene , cumene hydroperoxide , catalysis , chemistry , alkylation , distillation , benzene , chemical engineering , organic chemistry , engineering
Alkylation reactions of benzene with propylene using zeolites were studied for their affinity for cumene production. The current process for the production of cumene involves heating corrosive acid catalysts, cooling, transporting, and distillation. This study focused on the reaction of products in a static one-pot vessel using non-corrosive zeolite catalysts, working towards a more efficient one-step process with a potentially large energy savings. A series of experiments were conducted to find the best reaction conditions yielding the highest production of cumene. The experiments looked at cumene formation amounts in two different reaction vessels that had different physical traits. Different zeolites, temperatures, mixing speeds, and amounts of reactants were also investigated to find their affects on the amount of cumene produced. Quantitative analysis of product mixture was performed by gas chromatography. Mass spectroscopy was also utilized to observe the gas phase components during the alkylation process

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