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Final report of research supported by DOE Grant No. DE-FG02-96ER14635: Photochemical studies of two component systems within the restricted spaces of zeolites.
Author(s) -
V. Ramamurthy
Publication year - 2002
Language(s) - English
Resource type - Reports
DOI - 10.2172/771227
Subject(s) - context (archaeology) , component (thermodynamics) , reagent , environmentally friendly , zeolite , molecule , chemistry , nanotechnology , combinatorial chemistry , materials science , organic chemistry , catalysis , physics , geology , paleontology , ecology , biology , thermodynamics
Most chemistry in nature occurs within a closed and confined space. In contrast to this time-evolved [m?] organic chemists have focused their interests in developing reaction methods in solution. The price for this is paid in terms of non-selectivity in product formation, expensive reagents, and enormous wastes. Eventually 'man-developed' solution methods to make molecules have to be replaced by more selective, more environmentally friendly, and less expensive strategies. One approach in this direction would be to use controlled environments. The project focused towards developing energy efficient methods to prepare energy rich molecules that were useful to the public. In this context synthetic zeolites, the counterpart of naturally occurring minerals, were explored as the reaction media

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