Synthesis and characterization of metal--metal bonded dimers of tantalum and tungsten | Zendy

Joseph L. Templeton | Zendy

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Synthesis and characterization of metal--metal bonded dimers of tantalum and tungsten

Author(s) -

Joseph L. Templeton

Publication year - 1975

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/7299674

Subject(s) - tantalum , metal , tungsten , halide , characterization (materials science) , crystallography , materials science , metal halides , dimer , chemistry , polymer chemistry , inorganic chemistry , metallurgy , nanotechnology , organic chemistry

A search for innovative synthetic routes to new metal-metal bonded metal-halide clusters resulted in isolation of two completely independent dimeric species. The syntheses and characterizations of Ta/sub 2/X/sub 6/(SC/sub 4/H/sub 8/)/sub 3/ (X = Cl, Br) and ((n-C/sub 3/H/sub 7/)/sub 4/N)/sub 2/(W/sub 2/Br/sub 9/) followed entirely different experimental routes, yet occasionally similar properties linked the two projects. (auth)

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