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Molecular detection using Rydberg, autoionizing, and cluster states. Progress report
Author(s) -
John E. Wessel
Publication year - 1989
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/674622
Subject(s) - trimer , autoionization , rydberg formula , atomic physics , ionization , photoionization , cluster (spacecraft) , tetramer , photoemission spectroscopy , chemistry , excitation , spectroscopy , molecular physics , physics , x ray photoelectron spectroscopy , dimer , ion , nuclear magnetic resonance , biochemistry , enzyme , organic chemistry , quantum mechanics , computer science , programming language
Continuing investigations of multiphoton ionization processes in naphthalene have established the geometry and spectroscopy of trimer and tetramer cluster states. A new, highly efficient ionization mechanism has been identified in the trimer. It is closely related to autoionization of 2-electron atoms by resonant 2-photon excitation and to exciton fusion in larger clusters

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