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Temperature effects on the performance of PMAN-derived carbon anodes in 1M LiPF{sub 6}/EC-DMC solution
Author(s) -
R.A. Guidotti,
B.J. Johnson
Publication year - 1998
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/672103
Subject(s) - dimethyl carbonate , ethylene carbonate , copolymer , carbon fibers , carbonate , kinetics , divinylbenzene , chemistry , materials science , analytical chemistry (journal) , chemical engineering , inorganic chemistry , organic chemistry , styrene , catalysis , composite number , electrode , electrolyte , polymer , physics , quantum mechanics , engineering , composite material
The effect of temperature on the reversible and irreversible capacities of disordered carbons derived from polymethacryonitrile (PMAN) and divinylbenzene (DVB) copolymers was studied in 1 M LiPF{sub 6}/ethylene carbonate (EC)-dimethyl carbonate (DMC) (1:1 v/v) solution by galvanostatic cycling. The kinetics of passive film formation were examined by complex-impedance spectroscopy. Temperatures of 5, 21, and 35 C were used in the study

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