Pretreatment of americium/curium solutions for vitrification
Author(s) -
Tracy S. Rudisill
Publication year - 1996
Publication title -
osti oai (u.s. department of energy office of scientific and technical information)
Language(s) - English
Resource type - Reports
DOI - 10.2172/565235
Subject(s) - vitrification , curium , americium , nitric acid , radiochemistry , lanthanide , precipitation , fission products , oxalate , actinide , chemistry , nuclear chemistry , plutonium , inorganic chemistry , nuclear physics , ion , physics , organic chemistry , meteorology
Vitrification will be used to stabilize an americium/curium (Am/Cm) solution presently stored in F-Canyon for eventual transport to the heavy isotope programs at Oak Ridge National Laboratory. Prior to vitrification, an in-tank oxalate precipitation and a series of oxalic/nitric acid washes will be used to separate these elements and lanthanide fission products from the bulk of the uranium and metal impurities present in the solution. Pretreatment development experiments were performed to understand the behavior of the lanthanides and the metal impurities during the oxalate precipitation and properties of the precipitate slurry. The results of these experiments will be used to refine the target glass composition allowing optimization of the primary processing parameters and design of the solution transfer equipment
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