Catalytic applications of mono- and dinuclear complexes containing metal-carbon sigma bonds. Final report, November 1, 1993--October 31, 1996 | Zendy

Jack R. Norton | Zendy

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Catalytic applications of mono- and dinuclear complexes containing metal-carbon sigma bonds. Final report, November 1, 1993--October 31, 1996

Author(s) -

Jack R. Norton

Publication year - 1996

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/541813

Subject(s) - osmium , protonation , catalysis , chemistry , ethylene , metal , fragmentation (computing) , carbon fibers , photochemistry , polymer chemistry , ruthenium , organic chemistry , materials science , ion , composite number , computer science , composite material , operating system

This report discusses results from several studies involved in the project. Investigations include: vibrational models for surface olefins and alkylidenes; mechanism of the formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; determination by nematic phase NMR of the structure of mononuclear and dinuclear ethylene complexes of osmium; and generation of ``coordinatively unsaturated`` complexes by protonation of methyl osmium complexes

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