Metallacumulenes and carbide complexes. Final performance report | Zendy

John P. Selegue | Zendy

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Metallacumulenes and carbide complexes. Final performance report

Author(s) -

John P. Selegue

Publication year - 1992

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/516449

Subject(s) - transition metal , carbide , carbon fibers , fullerene , carbene , hydrodesulfurization , polythiophene , metal , catalysis , polymer , chemistry , materials science , polymer chemistry , organic chemistry , conductive polymer , composite number , composite material

We investigated many aspects of transition metal complexes of carbon-rich ligands, including cumulated transition metal carbene complexes of the types vinylidene (M=C=CR{sub 2})(M = Fe, Ru, Os, Mo, W), allenylidene (M=C=C=CR{sub 2}), and butatrienylidene (M=C=C=CR{sub 2}), as well as ``naked`` carbon ligands C{sub 1}, C{sub 2}, and C{sub 3}. In the last 3 years, we began to put some effort into studying the fullerenes. Finally, we investigated initial aspects of the coordination chemistry of thiophenes, from the perspectives of (1) modeling the transition- metal-catalyzed hydrodesulfurization of fossil fuels and (2) development of metal-doped, polythiophene-based polymers

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