Excess Sodium Tetraphenylborate and Intermediates Decomposition Studies | Zendy

M.J. Barnes | Zendy

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Excess Sodium Tetraphenylborate and Intermediates Decomposition Studies

Author(s) -

M.J. Barnes

Publication year - 1998

Publication title -

osti oai (u.s. department of energy office of scientific and technical information)

Language(s) - English

Resource type - Reports

DOI - 10.2172/4872

Subject(s) - sodium tetraphenylborate , chemistry , decomposition , tetraphenylborate , benzene , sodium , inorganic chemistry , reactivity (psychology) , palladium , catalysis , ion , organic chemistry , pathology , medicine , alternative medicine

The stability of excess amounts of sodium tetraphenylborate (NaTPB) in the In-Tank Precipitation (ITP) facility depends on a number of variables. Concentration of palladium, initial benzene, and sodium ion as well as temperature provide the best opportunities for controlling the decomposition rate. This study examined the influence of these four variable on the reactivity of palladium-catalyzed sodium tetraphenylborate decomposition. Also, single effects tests investigated the reactivity of simulants with continuous stirring and nitrogen ventilation, with very high benzene concentrations, under washed sodium concentrations, with very high palladium concentrations, and with minimal quantities of excess NaTPB

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