Organic and TRU screening for 200 West Area SST interim stabilization activities

This SD documents the preliminary work performed during the effort to better understand the magnitude and nature of transuranic (TRU) and/or complexed wastes contained in the 200 West Area single shell tank (SSTs). This preliminary work identified which of the SST interstitial liquids in question had adequate characterizations and performed a limited compatibility assessment based upon those characterizations. This allowed a determination of the TRU activity in the liquid and the waste type which describes the liquid. The waste type, complexed or non-complexed, was determined by a calculated total organic carbon (TOC) concentration when the waste containing the measured TOC value is evaporated to the composition of double-shell slurry feed (DSSF). DSSF was defined as the concentration at which aluminum bearing solids begin to precipitate (the sodium aluminate boundary), or when the OH concentration reached 8.0 as determined by the PREDICT evaporator simulation program. Two sets of results are presented. The first set identified only those tanks with adequate characterization data, and listed the remaining tanks as unknowns. These results have the higher level of confidence. The second result set used engineering judgement to estimate applicable characterization data where none existed. This allowed a tentative classification to be made for all but one of the tanks considered unknowns from the first result set. These results may have utility if decisions must be made in the absence additional, improved waste characterizations. This information was used in developing the follow-on laboratory testing to more precisely defined the magnitude and specifics of the compatibility problems