
Detection and quantitative analysis of chemical species in Hanford tank materials using Raman spectroscopy technology: FY94, January 1, 1994--March 31, 1995
Author(s) -
Thomas J. Vickers,
Charles K. Mann
Publication year - 1995
Language(s) - English
Resource type - Reports
DOI - 10.2172/441100
Subject(s) - raman spectroscopy , analytical chemistry (journal) , materials science , absorption (acoustics) , particle (ecology) , spectroscopy , environmental science , optics , chemistry , environmental chemistry , composite material , physics , geology , oceanography , quantum mechanics
This report provides a summary of work completed in FY-94 by FSU to develop and investigate the feasibility of using Raman spectroscopy with Hanford tank waste materials. Raman performance impacts from sample morphology, including the effects of absorption, particle size, density, color and refractive index, are discussed. An algorithm for relative species concentration measurement from Raman data is presented. An Algorithm for applying Raman to tank waste core screening is presented and discussed. A library of absorption and Raman spectra are presented that support this work