Open AccessTechnology development for iron Fischer-Tropsch catalysis. Quarterly technical progress report No. 7, April 1, 1996--June 30, 1996
Author(s) -
Burtron H. Davis
Publication year - 1996
Language(s) - English
Resource type - Reports
DOI - 10.2172/432841
Subject(s) - fischer–tropsch process , catalysis , slurry , characterization (materials science) , work (physics) , process engineering , syngas , chemical engineering , selectivity , materials science , chemistry , engineering , mechanical engineering , nanotechnology , organic chemistry , composite material
The objective of this research project is to develop the technology for the production of physically robust iron-based Fischer-Tropsch catalysts that have suitable activity, selectivity and stability to be used in the slurry phase synthesis reactor development. The catalysts that are developed shall be suitable for testing in the Advanced Fuels Development Facility at LaPorte, Texas, to produce either low- or high-alpha product distributions. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the ``standard-catalyst`` developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst this is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics. The research is divided into four major topical areas: (a) catalyst preparation and characterization, (b) product characterization, (c) reactor operations, and (d) data assessment